
有机光电材料研究所 所长
秦天石,博士生导师
南京工业大学先进材料研究院研究员
国家重点研发计划课题负责人
联系方式:
邮箱:iamtsqin@njtech.edu.cn
地址:南京工业大学丁家桥校区教学楼411-1
研究方向:
有机光伏材料,有机半导体材料,有机合成,纳米金属材料,纳米过渡金属氧化物材料。尤其擅长有机光伏材料的设计与合成,印刷光伏电池浆料配方调配与制备,器件结构优化。在J AM CHEM SOC, ANGEW CHEM, ENERG ENVIRON SCI, ADV MATER, NANO ENERGY等高影响力学术期刊发表论文近20篇,他引超过600次。其中7篇入选ESI高被引。先后参与了澳洲联邦政府与维多利亚州政府的印刷柔性太阳能电池重大研究项目,负责核心印刷光伏材料的设计与制备。开发出多种印刷光伏墨水并获多项国际专利授权,基于本人开发的印刷柔性光伏电池于2014年澳洲G20峰会公开展示。
国际专利:
1.Tianshi Qin, Scott Watkins. A-D1-A-D2 Conjugated Polymers for Organic Solar Cells, International Patent, PCT/AU2014/000761, 国际专利号 WO2015013747A1.
2.Tianshi Qin, Electroactive materials, printing compositions and methods of manufacturing solar cells, Provisional International Patent, 国际专利申请号 TW8926/Prov 23/11/2015.
3.Tianshi Qin, Roland Bauer, Klaus Müllen. Blue Light Emitting Polytriphenylene Dendrimers, Methods of Preparation and Uses thereof, European Patent, 欧洲专利号 EP2143775A1.
代表性论文:
1.Tianshi Qin*, Wenchao Huang, Jueng-Eun Kim, Doojin Vak, Craig Forsyth, Christopher R. McNeill, Yi-Bing Cheng*. Amorphous hole-transporting layer in slot-die coated perovskite solar cells. Nano Energy, 2017, 31, 210.
2.Tianshi Qin*, Wojciech Zajaczkowski, Wojciech Pisula, Martin Baumgarten, Ming Chen, Mei Gao, Gerry Wilson, Christopher D. Easton, Klaus Müllen, Scott Watkins. Tailored Donor-Acceptor Polymers with an A-D1-A-D2 Structure: Controlling Intermolecular Interactions to Enable Enhanced Polymer Photovoltaic Devices. Journal of American Chemical Society, 2014, 136, 6049.
3.Tianshi Qin, Wolfgang Wiedemair, Sebastian Nau, Roman Trattnig, Stefan Sax, Stefanie Winkler, Antje Vollmer, Norbert Koch, Martin Baumgarten, Emil J. W. List, Klaus Müllen, Pyrene cored polytriphenylene dendrimers: Core, Shell, and Surface-Optimized Dendrimers for Blue Light-Emitting Diodes, Journal of American Chemical Society, 2011, 133, 1301.
4.Tianshi Qin, Junqiao Ding, Lixiang Wang, Martin Baumgarten, Gang Zhou, Klaus Müllen. A Divergent Synthesis of Very Large Polyphenylene Dendrimers with Iridium(III) Cores: Molecular Size Effect on the Performance of Phosphorescent Organic Light-Emitting Diodes, Journal of American Chemical Society, 2009, 131, 14329.
5.Tianshi Qin, Gang Zhou, Horst Scheiber, Roland E. Bauer, Martin Baumgarten, Christopher E. Anson, Emil J. W. List, Klaus Müllen. Polytriphenylene Dendrimers: A Unique Design for Blue-Light-Emitting Materials, Angewandte Chemie International Edition, 2008, 47, 8292.
6.Tianshi Qin, Junqiao Ding, Lixiang Wang, Martin Baumgarten, Gang Zhou, Klaus Müllen. High-effiency Red Phosphorescent Organic Light-Emitting Diodes Based on Iridium(III) Cored Polyphenylene Dendrimers, Macromolecular Rapid Communications, 2012, 33, 1036.
7.Kedar D. Deshmukh, Tianshi Qin, Joseph K. Gallaher, Amelia C. Y. Liu, Eliot Gann, Kane O'Donnell, Lars Thomsen, Justin M. Hodgkiss, Scott E. Watkins and Christopher R. McNeill*. Performance, morphology and hotophysics of high open-circuit voltage, low band gap all-polymer solar cells. Energy & Environmental Science. 2015, 8, 332-342.
8.Jegadesan Subbiah, Balaji Purushothaman, Ming Chen, Tianshi Qin, Mei Gao, Doojin Vak, Fiona H. Scholes, Xiwen Chen, Scott E. Watkins, Gerard J. Wilson, Andrew B. Holmes, Wallace W. H. Wong,* and David J. Jones*. Organic Solar Cells Using a High-Molecular-Weight Benzodithiophene–Benzothiadiazole Copolymer with an Efficiency of 9.4%. Advanced Materials, 2015, 27, 702-705.
9.Mei Gao*, Jegadesan Subbiah, Paul B. Geraghty, Ming Chen, Balaji Purushothaman, Xiwen Chen, Tianshi Qin, Doojin Vak, Fiona H. Scholes, Scott E. Watkins, Melissa Skidmore, Gerard J. Wilson, Andrew B. Holmes, David J. Jones*, Wallace W. H. Wong*. Development of a High-Performance Donor-Acceptor Conjugated Polymer: Synergy in Materials and Device Optimization. Chemistry of Materials. 2016, 28, 3481-3487.
10.Zeyun Xiao, Kuan Sun, Jegadesan Subbiah, Tianshi Qin, Shirong Lu, Balaji Purushothaman, David J Jones, Andrew B Holmes, Wallace W H Wong*. Effect of molecular weight on the properties and organic solar cell device performance of a donor–acceptor conjugated polymer. Polymer Chemistry, 2015, 6, 2312-2318.
11.Xiaoxi He, Subhrangsu Mukherjee, Scott Watkins, Ming Chen, Tianshi Qin; Lars Thomsen, Harald Ade, Christopher R. McNeill. Influence of Fluorination and Molecular Weight on the Morphology and Performance of PTB7:PC71BM Solar Cells. Journal of Physical Chemistry C. 2014, 118, 9918.
12.Shuping Pang, Hao Hu, Jiliang Zhang, Siliu Lv, Yaming Yu, Feng Wei, Tianshi Qin, Hongxia Xu, Zhihong Liu, Guanglei Cui, NH2CH=NH2PbI3: An Alternative Organolead Iodide Perovskite Sensitizer for Mesoscopic Solar Cells. Chemistry of Materials. 2014, 26, 1485.
13.Matthias Georg Schwab, Tianshi Qin, Wojciech Pisula, Alexey Mavrinskiy, Xinliang Feng, Martin Baumgarten, Hun Kim, Frédéric Laquai, Sebastian Schuh, Roman Trattnig, Emil J. W.?List, Klaus Müllen. Molecular Triangles: Synthesis, Self-Assembly, and Blue Emission of Cyclo-7,10-tris-triphenylenyl Macrocycles, Chemistry - An Asian Journal, 2011, 6, 3001.